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Molecular Beam Studied of 3-C3H5Br and 1-C3H5Br. Competition.......

日期:2016-08-25

题名:Molecular Beam Studied of 3-C3H5Br and 1-C3H5Br. Competition Between Photodissociation and Isomerization

摘要:The photodissociation of 3-C3H5Br and 1-C3H5Br at 193 nm was studied by TOF technique in a pulsed molecular beam apparatus. The center-of-mass translational energy distribution P (Et) was obtained by simulation fitting the experimental TOF spectra. Evidence was found for competition of hydrogen migration leading to isomerization, with dissociation of 1- C3H5Br. Rich intramolecular dynamics indicated by the experimental observation were discussed.

作者: Zhu Wu-Sheng, Zhao Xin-Sheng, Han De-Gang, Li Run-Jun, Zhong Qing-Hua, Zhu Qi-He

来源(出处):Chem. Phys. Lett., Vol.204, P538-542(1993).

发表日期:1993

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Molecular Beam Studied of 3-C3H5Br and 1-C3H5Br. Competition.......

日期:2016-08-25

题名:Molecular Beam Studied of 3-C3H5Br and 1-C3H5Br. Competition Between Photodissociation and Isomerization

摘要:The photodissociation of 3-C3H5Br and 1-C3H5Br at 193 nm was studied by TOF technique in a pulsed molecular beam apparatus. The center-of-mass translational energy distribution P (Et) was obtained by simulation fitting the experimental TOF spectra. Evidence was found for competition of hydrogen migration leading to isomerization, with dissociation of 1- C3H5Br. Rich intramolecular dynamics indicated by the experimental observation were discussed.

作者: Zhu Wu-Sheng, Zhao Xin-Sheng, Han De-Gang, Li Run-Jun, Zhong Qing-Hua, Zhu Qi-He

来源(出处):Chem. Phys. Lett., Vol.204, P538-542(1993).

发表日期:1993